What is phosphogypsum?

Gypsum is a mineral that occurs in nature.

Phosphogypsum refers to the gypsum formed as a by-product of processing phosphate ore into fertilizer with sulfuric acid.

It is radioactive due to the presence of naturally occurring uranium and radium in the phosphate ore.


Gypsum is a mineral that occurs in nature and as a by-product of many industrial processes. Gypsum is commonly used in industrial and agricultural applications worldwide.

Phosphogypsum refers specifically to the gypsum formed as a by-product of processing phosphate ore into fertilizer with sulfuric acid. As with almost all sources of gypsum, phosphogypsum contains impurities. Phosphogypsum may contain low residual concentrations of radium from the source rock (and other metals) and hence can potentially have a level of radioactivity associated with radon gas.

Inconsistent regulation


here is inconsistent regulation regarding phosphogypsum on a global level. Typically phosphogypsum is stacked in above ground storage facilities termed gypstacks. Recently the International Atomic Energy Agency (IAEA) has released a new study (March 2013) that provides a framework for safe and sustainable use of phosphogypsum based on current health and science information. The IAEA study utilizes a risk based criteria for use.

Where utilized, phosphogypsum is most commonly used as raw material, fertilizer, soil conditioner, road building, landfill cover, glass/ceramic, and housing. Excellent examples of sustainable reuse are present in Brazil, India, China, and Tunisia.

Source of sulphur


An important aspect regarding phosphogypsum is its potential to solve sulphur deficiency in soils. While elemental sulphur and organic sulphur must undergo microbial conversion before sulphur is made available to plant, the sulphur in phosphogypsum becomes readily available for being present in sulphate form.

Matching source and end use


The residual radium and metal concentrations of phosphogypsum depends on the source of rock used and the processing conditions. Consequently, risk management principles must be taken to match a given source of phosphogypsum to the appropriate end use. IFA promotes uniformization of regulations regarding the handling, storage and use of this by-product so that its potential may be used effectively, while its associated risks are minimized.
 
Phosphogypsum bibliography
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Use of Phosphogypsum in Agriculture in China - Read More ... Chuan, L.2017MemberDownload
2016 Phosphogypsum agricultural uses in southern Brazil - Read More ... Caires, E.F., Inagaki, T.M., Guimaraes, A.M.2016MemberDownload
Phosphogypsum Update Zero Waste – Threat or Opportunity? A Full Cost Accounting Approach to the Answer - Read More ... Hilton, J.2016MemberDownload
Phosphogypsum: Sustainable Management and Use - Read More ... Birky, B., Hilton, J., Johnston, AE J.2016MemberOrder
Utilization of Phosphogysum in Road Making - Read More ... Misra, R.2016MemberDownload

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